The trick is having clear synch-points. It can be an obvious drum beat in the intro and one at the end, the singer shouting out "thank-you and goodnight", whatever, as long as you hear it when soloing the video and the separate audio and you can see that event in the peak waveforms. Record some test pieces and we can help you through the aligning process. It really is quite easy unless you've recorded 55 minutes of flies buzzing monotonously. I've done this dozens of times for live gig videos where there is a single camera. >